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The impact of fluoride on Al abundance and speciation in boreal streams
Linnéuniversitetet, Fakulteten för Hälso- och livsvetenskap (FHL), Institutionen för biologi och miljö (BOM).
Linnéuniversitetet, Fakulteten för Hälso- och livsvetenskap (FHL), Institutionen för biologi och miljö (BOM).
Swedish University of Agricultural Sciences;KTH Royal Inst Technol.
Linnéuniversitetet, Fakulteten för Hälso- och livsvetenskap (FHL), Institutionen för biologi och miljö (BOM).
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2015 (Engelska)Ingår i: Chemical Geology, ISSN 0009-2541, E-ISSN 1872-6836, Vol. 409, s. 118-124Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

The impact of fluoride on the abundance and speciation of aluminium (Al) was investigated in three boreal streams characterised by overall high concentrations of fluoride and dissolved organic matter. Stream-water sampling was carried out several times a year for at least 4 years, and a chemical equilibrium model (Visual MINTEQ) was applied in order to model the proportion of colloidal and organically/inorganically complexed Al in the waters. The Al concentrations in filtered (0.45 mu m) water samples were inversely correlated with pH, and reached values up to approximately 1 mg/L during low pH conditions (pH < 6.0). In a stream with high fluoride concentrations, as compared to a similar stream with only moderately elevated fluoride concentrations, the Al concentrations were consistently elevated. For the stream with high concentrations of fluoride and Al, the model predicted both high concentrations and proportions of Al-fluoride complexation. This prediction indicates that high fluoride levels contribute to raise both the Al abundance and the ratio of inorganic to organic Al complexation in stream water. In contrast, for another stream with high fluoride concentrations and consistently high (near neutral) pH, there was no evidence of fluoride affecting Al concentration or complexation. These results show that it is important to focus future studies on the role of high levels of dissolved fluoride on both the speciation and the toxicity of Al in stream water.

Ort, förlag, år, upplaga, sidor
2015. Vol. 409, s. 118-124
Nationell ämneskategori
Miljövetenskap
Forskningsämne
Naturvetenskap, Miljövetenskap
Identifikatorer
URN: urn:nbn:se:lnu:diva-44138DOI: 10.1016/j.chemgeo.2015.05.013ISI: 000358525500012Scopus ID: 2-s2.0-84930942419OAI: oai:DiVA.org:lnu-44138DiVA, id: diva2:820655
Tillgänglig från: 2015-06-12 Skapad: 2015-06-12 Senast uppdaterad: 2019-01-23Bibliografiskt granskad
Ingår i avhandling
1. Fluoride in surface water and groundwater in southeast Sweden: sources, controls and risk aspects
Öppna denna publikation i ny flik eller fönster >>Fluoride in surface water and groundwater in southeast Sweden: sources, controls and risk aspects
2016 (Engelska)Doktorsavhandling, sammanläggning (Övrigt vetenskapligt)
Abstract [en]

The aim of this thesis is to determine the sources, controls and risk aspects of fluoride in surface water and groundwater in a region of southeastern Sweden where the fluorine-rich 1.45 Ga circular Götemar granite (5 km in diameter) crops out in the surrounding 1.8 Ga granites and quartz monzodiorites (TIB rocks). The materials of this thesis include both primary data, collected for the purpose of this thesis, and a large set of secondary data, retrieved from the Swedish Nuclear Fuel and Waste Management Co., the Swedish Geological Survey and the Kalmar County Council. A characteristic feature of the area is high fluoride concentrations in all kinds of natural waters, including surface waters (such as streams) and groundwater in both the Quaternary deposits (regolith groundwater) and bedrock fractures (fracture groundwater). A number of potential sources and controls of the high fluoride concentrations were investigated, including a variety of geological, mineralogical, mineral-chemical and hydrological features and processes. For the stream waters and regolith groundwater, high fluoride concentrations were correlated with the location of the Götemar granite. This finding is explained by the discharge of fluoride-rich groundwater from fractures in the bedrock and/or the release of fluoride due to the weathering of fluorine-bearing minerals in the Quaternary deposits; however, the Quaternary deposits had considerably lower fluoride concentrations than the underlying bedrock. The high fluoride concentrations in the fresh fracture groundwater (up to 7.4 mg/L) in the TIB-rocks are proposed to be the result of long residence times and the alteration/dissolution of fluorine-bearing primary and secondary minerals along the fracture walls. In terms of risk aspects, this thesis shows that fluoride can add to the transport and inorganic complexation of aluminium in humic-rich, acidic streams. Additionally, 24 % of the children in households with private wells in Kalmar County were assessed to be at risk of excess fluoride intake based on the WHO drinking water guideline value (1.5 mg/L). However, the risk increased significantly when instead the US EPA reference dose (0.06 mg/kg-day) was used, both when all relevant exposure pathways were taken into account as well as water consumption alone. Hence, it is shown that the risk of an excess intake of fluoride is strongly dependent on the basis for evaluation.

Ort, förlag, år, upplaga, sidor
Växjö: Linnaeus University Press, 2016
Serie
Linnaeus University Dissertations ; 253/2016
Nyckelord
fluorine, fluoride, water-rock interaction, granite, crystalline bedrock, surface water, groundwater, Götemar, drinking water quality, aluminium, speciation, fluorosis, PBA
Nationell ämneskategori
Miljövetenskap
Forskningsämne
Naturvetenskap, Miljövetenskap
Identifikatorer
urn:nbn:se:lnu:diva-52562 (URN)978-91-88357-20-5 (ISBN)
Disputation
2016-06-10, Fullriggaren, Sjöfartshögskolan, Kalmar, 09:30 (Svenska)
Opponent
Handledare
Tillgänglig från: 2016-05-20 Skapad: 2016-05-18 Senast uppdaterad: 2016-11-22Bibliografiskt granskad

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