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Cobalt-Catalyzed Oxidative Annulation of Berizothiophene-[b]-1,1-dioxide through Diastereoselective Double C-H Activation
Linnaeus University, Faculty of Health and Life Sciences, Department of Chemistry and Biomedical Sciences. (Linnaeus Ctr Biomat Chem, BMC)ORCID iD: 0000-0003-0774-2528
Linnaeus University, Faculty of Health and Life Sciences, Department of Chemistry and Biomedical Sciences. (Linnaeus Ctr Biomat Chem, BMC)ORCID iD: 0000-0002-0407-6542
2019 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 21, no 24, p. 9806-9811Article in journal (Refereed) Published
Abstract [en]

The use of inexpensive base metal catalysis to perform C H activation is an active field of research in organic synthesis. Described herein is a sustainable cobaltcatalyzed diastereoselective oxidative annulation/double C H activation of benzothiophene-[b]-1,1-dioxide with aminoquinolinamides under mild reaction conditions for the synthesis of annulated benzothiophenes.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2019. Vol. 21, no 24, p. 9806-9811
National Category
Organic Chemistry
Research subject
Chemistry, Organic Chemistry
Identifiers
URN: urn:nbn:se:lnu:diva-91026DOI: 10.1021/acs.orglett.9b03158ISI: 000504805500002PubMedID: 31651175OAI: oai:DiVA.org:lnu-91026DiVA, id: diva2:1386831
Available from: 2020-01-20 Created: 2020-01-20 Last updated: 2020-01-20Bibliographically approved

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Kathiravan, SuppanNicholls, Ian A.

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