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Chemical extraction of trace elements from dredged sediments into a circular economy perspective: Case study on Malmfjärden Bay, south-eastern Sweden
Linnaeus University, Faculty of Health and Life Sciences, Department of Biology and Environmental Science. (ESEG group)ORCID iD: 0000-0002-0367-5332
Malmö University, Sweden.ORCID iD: 0000-0001-8906-9271
Linnaeus University, Faculty of Health and Life Sciences, Department of Biology and Environmental Science. Linnaeus University, Linnaeus Knowledge Environments, Water. (ESEG group)ORCID iD: 0000-0002-1903-760X
2021 (English)In: Resources, Environment and Sustainability, E-ISSN 2666-9161, Vol. 6, article id 100039Article in journal (Refereed) Published
Sustainable development
SDG 2: End hunger, achieve food security and improved nutrition, and promote sustainable agriculture, SDG 14: Conserve and sustainably use the oceans, seas and marine resources for sustainable development, SDG 15: Protect, restore and promote sustainable use of terrestrial ecosystems, sustainably manage forests, combat desertification, and halt and reverse land degradation and halt biodiversity loss, SDG 12: Ensure sustainable consumption and production patterns
Abstract [en]

Worldwide, sediments are dredged from water bodies to guarantee proper water levels and remediate aquatic ecosystems. Dredged sediments contain metals that could interfere with recycling if the concentrations overpass permissible limits. Washing of elements from sediments represents a technique to decrease the concentration of metals, and it could introduce a new source of elements. The current study aimed to employ ethylenediamine-tetraacetic acid (EDTA) and ethylenediamine-disuccinic acid (EDDS) and investigate the effect of operational parameters (concentration and pH) on the chemical extraction of metals from dredged sediments. Core sediments were extracted from sampling stations around Malmfjärden bay, Sweden. The results suggested that lead, zinc and copper were the elements with higher extraction rates, followed by arsenic and nickel. Chromium was poorly extracted. EDTA was more efficient than EDDS in dissolving the elements. Moreover, acidic conditions offered higher extraction rates for As using both chelators and for Pb employing EDTA. The 0.05 M concentration presented a higher mean extraction rate than 0.01 M for Cu, Cr and Ni for EDTA and EDDS. The findings in this study suggest that sediment washing is a promising technique to decrease metal concentrations in sediments and enhancing the feasibility to use the material for beneficial uses.

Place, publisher, year, edition, pages
Elsevier, 2021. Vol. 6, article id 100039
National Category
Environmental Sciences
Research subject
Natural Science, Environmental Science
Identifiers
URN: urn:nbn:se:lnu:diva-109599DOI: 10.1016/j.resenv.2021.100039ISI: 001134594800001Scopus ID: 2-s2.0-85117382443Local ID: 2021OAI: oai:DiVA.org:lnu-109599DiVA, id: diva2:1630366
Funder
Swedish Agency for Marine and Water ManagementAvailable from: 2022-01-20 Created: 2022-01-20 Last updated: 2024-03-13Bibliographically approved
In thesis
1. Sustainable management of dredged sediments: potential recovery of valuable compounds
Open this publication in new window or tab >>Sustainable management of dredged sediments: potential recovery of valuable compounds
2022 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Dredging of sediments occurs worldwide to increase water depth in harbours, bays, lakes and rivers, as well as to recover aquatic ecosystems. Landfilling and open-ocean discharge are traditional disposal routes for dredged material. However, the methods are restricted by environmental and legal concerns. Using dredged sediments for beneficial uses can contribute to implementing circular economies and avoiding traditional disposal methods. This thesis aimed to contribute to the sustainable management of dredged sediments by increasing the knowledge of the beneficial use of the material. The work focused on Malmfjärden bay, located in Kalmar, Sweden, which is currently shallow and presents a high concentration of nutrients. The LIFE SURE project aimed to dredge the bay and use the dredged material for beneficial purposes.

The results from the thesis showed a high potential to use Malmfjärden sediments for beneficial uses. The first step involved the characterisation of sediments, which showed a medium-high content of N and P was also present. The main pollution concerns were As, Pb and Cd, since their contents overpassed the Swedish limits for sensitive uses. The speciation and extraction of elements were also performed to assess their risk of pollution. The results showed that the most labile elements were Zn and Pb, and both presented the highest extraction rates using EDTA and EDDS. The results showed that the chemical extraction of metals could contribute to treating metal-polluted sediments and become a mining technique. Further studies focused on the recovery of nutrients from the sediments. They were mixed with compost, and lettuce grew in different substrates. However, the plants prematurely stopped growing, possibly due to the lack of available forms of N. Moreover, the harvested lettuces overpassed permissible contents for Cd, slightly threatening human health. It was shown that dredging could provide nutrients to soils, but the risk of metal pollution should be assessed. Finally, a life cycle assessment was calculated to assess the environmental impacts associated with landfilling Malmfjärden sediments or using the material in soil conditioning. Both scenarios presented negative impacts on global warming, eutrophication and toxicity categories. However, soil conditioning showed the most positive score due to the environmental savings of avoiding the production and use of fertilisers.

The thesis concludes by encouraging the performance of more interdisciplinary projects. This could combine the knowledge from several sectors to enhance the implementation of the beneficial use of dredged sediments.  

Place, publisher, year, edition, pages
Linnaeus University Press, 2022. p. 34
Series
Linnaeus University Dissertations ; 461
Keywords
Dredged sediments, nutrients, metals, speciation, recovery, characterisation, beneficial use, life cycle assessment, extraction, plant-growing substrate, circular economy
National Category
Environmental Management
Research subject
Natural Science, Environmental Science
Identifiers
urn:nbn:se:lnu:diva-116273 (URN)9789189709317 (ISBN)9789189709324 (ISBN)
Public defence
2022-09-16, Fullriggareb, Kalmar, 09:30 (English)
Opponent
Supervisors
Available from: 2022-09-15 Created: 2022-09-15 Last updated: 2025-03-06Bibliographically approved

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Ferrans, LauraJani, YahyaHogland, William

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