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Selenium-molybdenum-based colouration of alkali silicate glasses
Växjö University, Faculty of Mathematics/Science/Technology, School of Technology and Design.
Växjö University, Faculty of Mathematics/Science/Technology, School of Technology and Design.
Kemi, KTH.
MAX-lab, Lund.
2007 (English)In: Glass Technology, Eur J Glass Sci Technol A, ISSN 1753-3546, Vol. 48, no 5, p. 213-221Article in journal (Refereed) Published
Abstract [en]

The interaction between selenium and molybdenum in reduced alkali silicate melts, resulting in red glasses has been studied. The oxidation state of Mo is Mo(VI) as evidenced by XANES and ESCA results. Selenium is present in a reduced state, as inicated by ultraviolet/visible spectroscopy and XANES. The colour is described by ultraviolet/visible spectra and CIE colour coordinates. The main absorption peaks are at 450 and 540 nm. Similar bands are reported for MoOSe3 2-. Several commonly used glass components must be avoided in the batch, as they prevent formation of the red colour.

Place, publisher, year, edition, pages
Society of Glass Technology , 2007. Vol. 48, no 5, p. 213-221
Keywords [en]
glass, red colour, selenium-molybdenum
Identifiers
URN: urn:nbn:se:vxu:diva-2989OAI: oai:DiVA.org:vxu-2989DiVA, id: diva2:202945
Available from: 2008-01-02 Created: 2008-01-02 Last updated: 2011-01-11Bibliographically approved

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