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Rhodium(III)-catalysed, redox-neutral C(sp(2))-H alkenylation using pivalimide as a directing group with internal alkynes
Linnaeus University, Faculty of Health and Life Sciences, Department of Chemistry and Biomedical Sciences. (Ctr Biomat Chem)ORCID iD: 0000-0003-0774-2528
Linnaeus University, Faculty of Health and Life Sciences, Department of Chemistry and Biomedical Sciences. Uppsala University. (Ctr Biomat Chem)ORCID iD: 0000-0002-0407-6542
2017 (English)In: Tetrahedron Letters, ISSN 0040-4039, E-ISSN 1359-8562, Vol. 58, no 1, 1-4 p.Article in journal (Refereed) Published
Abstract [en]

In the presence of [RhCp*Cl(2)l(2), N-pivaloyl anilines react with internal alkynes to give the corresponding 2-alkenylpivalimides under redox neutral conditions through C-H activation. This redox neutral hydroarylation, which does not require an external organic acid, unlocks a regioselective synthetic route to 2-alkenyl anilines and is generally applicable to diversely substituted electron rich and electron poor pivalimides. (C) 2016 Elsevier Ltd. All rights reserved.

Place, publisher, year, edition, pages
2017. Vol. 58, no 1, 1-4 p.
Keyword [en]
Hydroarylation, Internal alkynes, Redox-neutral, Rhodium catalysis, Pivalimide
National Category
Chemical Sciences
Research subject
Natural Science, Chemistry
Identifiers
URN: urn:nbn:se:lnu:diva-60802DOI: 10.1016/j.tetlet.2016.11.039ISI: 000392038800001OAI: oai:DiVA.org:lnu-60802DiVA: diva2:1075978
Available from: 2017-02-21 Created: 2017-02-21 Last updated: 2017-04-20Bibliographically approved

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Kathiravan, SubbanNicholls, Ian A.

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