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Characterization and toxicity of hazardous wastes from an old Swedish glasswork dump
Linnaeus University, Faculty of Health and Life Sciences, Department of Biology and Environmental Science. (ESEG)ORCID iD: 0000-0001-8906-9271
Linnaeus University, Faculty of Health and Life Sciences, Department of Biology and Environmental Science.ORCID iD: 0000-0003-0269-4790
Linnaeus University, Faculty of Health and Life Sciences, Department of Biology and Environmental Science.
Linnaeus University, Faculty of Health and Life Sciences, Department of Biology and Environmental Science.ORCID iD: 0000-0002-7920-8001
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(English)Manuscript (preprint) (Other academic)
Abstract [en]

More than 34 old glasswork sites in the southeastern part of Sweden pose a permanent threat to human and environmental health due to the presence of toxic metals in open dumps with glass waste. The possibility of leaching of metals from different fractions of the disposed waste needed to be assessed. In the present investigation, leachate from fine fraction (soil plus glass particles < 2 mm) was characterized as following: pH (7.3), TOC (< 2%), organic content (4.4%), moisture content (9.7), COD (163 mg/kg) and trace elements content, being the values in accordance to the Swedish guidelines for landfilling of inert materials. However, very high metals content was found in the fine fraction as well as in all colors of the glass fraction (≥ 2 mm), whose values were compatible to hazardous waste landfill class. Tests with Lepidium sativum growing in the fine fraction as substrate revealed chronic toxicity expressed as inhibition of root biomass growth in 11 out of 15 samples. Additionally, leachate from fine fractions posed acute toxicity to genetically modified E. coli (Toxi-Chromotest). This study highlights the importance of combining physicochemical characterization with toxicity tests for both solid waste and leachate obtained from different waste fractions for proper hazardousness assessment supporting decision making on remediation demands.

Keywords [en]
Glass waste, old glassworks, trace elements, hazardous waste, ecotoxicity
National Category
Environmental Sciences
Research subject
Natural Science, Environmental Science
Identifiers
URN: urn:nbn:se:lnu:diva-69896OAI: oai:DiVA.org:lnu-69896DiVA, id: diva2:1174774
Available from: 2018-01-16 Created: 2018-01-16 Last updated: 2019-11-21Bibliographically approved
In thesis
1. Landfills and glass dumpsites as future bank accounts of resources: waste characterization and trace elements extraction
Open this publication in new window or tab >>Landfills and glass dumpsites as future bank accounts of resources: waste characterization and trace elements extraction
2018 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Environmental pollution and health threats as well as scarcity of raw materials, water, food and energy are among the main challenges our world are now facing. Simultaneously, landfills and open dumpsites still are the dominant global waste disposal option even with their long term environmental impacts in case of greenhouse gases and contaminated leachates. In this thesis, landfill mining is suggested as a tool that should be included in an enhanced circular economy model (repair, reuse and recycle + extract and recovery) by considering the extraction/recovery of the lost materials in landfills and dumpsites as secondary resources.

Characterization data (composition and physicochemical properties) is considered as a vital source for information for: i. the valorization of excavated wastes, ii. to explore potential hazards and iii. as an important tool for theassessment of the waste management systems and policies. In this thesis,excavated wastes from a classic landfill (Högbytorp in Sweden), a landfill buildup according to the European Directive requirements (Torma in Estonia) andhazardous glass dumpsite (Pukeberg in Sweden) was characterized as a centralstep in exploring the potential of recovering of valuables. In addition, the extraction of trace elements from waste glass and different finefractions were also investigated. The reduction-melting method was developedto extract hazardous concentrations of trace elements from old art and crystalglasses with more than (99%) of recovery of Pb, Cd and As. While threechelating agents (EDTA, DTPA and NTA) were used to extract Pb, Cd, Asand Zn from fine fraction (<2 mm) sampled from Pukeberg glasswork with anextraction efficiency of (40%). Besides, the fractionations of the metals Cu, Znand Cr in the fine fractions (<10 mm) excavated from Högbytorp and Tormalandfills were studied by using a modified sequential extraction procedure.

The findings of this thesis highlighted the need to consider the dumped wastesas secondary resources and landfills and dumpsites as future bank accounts offuture raw materials instead of being burden to the human health and theenvironment.

Place, publisher, year, edition, pages
Växjö: Linnaeus University Press, 2018. p. 26
Series
Linnaeus University Dissertations ; 308
Keywords
Landfill mining, metals extraction, glass dumpsites, hazardous waste, chemical extraction, reduction-melting
National Category
Environmental Sciences
Research subject
Natural Science, Environmental Science
Identifiers
urn:nbn:se:lnu:diva-69898 (URN)9789188761156 (ISBN)9789188761163 (ISBN)
Public defence
2018-02-02, 15:57 (English)
Opponent
Supervisors
Available from: 2018-01-17 Created: 2018-01-16 Last updated: 2024-02-21Bibliographically approved

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Jani, YahyaBurlakovs, JurisAugustsson, AnnaMarques, MarciaHogland, William

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