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Thermophysical Study of Binary Systems of tert-Amyl Methyl Ether with n-Hexane and m-Xylene
Linnaeus University, Faculty of Technology, Department of Built Environment and Energy Technology. Sultan Qaboos Univ, Oman.ORCID iD: 0000-0003-3732-9603
Sultan Qaboos Univ, Oman;Univ Tehran, Iran.
Univ Western Australia, Australia.
Sultan Qaboos Univ, Oman.
2019 (English)In: Journal of Chemical and Engineering Data, ISSN 0021-9568, E-ISSN 1520-5134, Vol. 64, no 2, p. 459-470Article in journal (Refereed) Published
Abstract [en]

This work presents the experimentally determined density (rho), viscosity (eta), speed of sound (u), and surface tension (sigma) data for tert-amyl methyl ether (TAME) + n-hexane and TAME + m-xylene systems at several temperatures (298.15, 308.15, 318.15, 323.15, and 328.15 K). These experimentally determined thermophysical data are utilized to compute various excess/deviation parameters such as molar volume (V-E), isentropic compressibility (K-s(E)), speed of sound (u(E)), deviation in viscosity (Delta In eta), isobaric thermal expansion coefficient (alpha(E)(P)), and surface tension (sigma(E)). The inspection of parameters response may interpret the existing specific molecular interactions as well as the mixing behavior of solutions. The critical analysis of observed parametric behavior have unveiled the strong and weak molecular interactions in TAME with m-xylene and TAME with n-hexane systems, respectively.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2019. Vol. 64, no 2, p. 459-470
National Category
Other Chemical Engineering Energy Engineering
Research subject
Technology (byts ev till Engineering), Bioenergy Technology
Identifiers
URN: urn:nbn:se:lnu:diva-81095DOI: 10.1021/acs.jced.8b00589ISI: 000459224500010Scopus ID: 2-s2.0-85062014917OAI: oai:DiVA.org:lnu-81095DiVA, id: diva2:1296454
Available from: 2019-03-15 Created: 2019-03-15 Last updated: 2019-08-29Bibliographically approved

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Ahmad, Waqar

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