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Non-Ionic Deep Eutectic Liquids: Acetamide-Urea Derived Room Temperature Solvents
Linnaeus University, Faculty of Health and Life Sciences, Department of Chemistry and Biomedical Sciences. (Linnaeus Ctr Biomat Chem, BMC)
Linnaeus University, Faculty of Health and Life Sciences, Department of Chemistry and Biomedical Sciences. (Linnaeus Ctr Biomat Chem, BMC)ORCID iD: 0000-0003-4037-1992
Linnaeus University, Faculty of Health and Life Sciences, Department of Chemistry and Biomedical Sciences. (Linnaeus Ctr Biomat Chem, BMC)ORCID iD: 0000-0003-0774-2528
Linnaeus University, Faculty of Health and Life Sciences, Department of Chemistry and Biomedical Sciences. (Linnaeus Ctr Biomat Chem, BMC)
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2019 (English)In: International Journal of Molecular Sciences, ISSN 1422-0067, E-ISSN 1422-0067, Vol. 20, no 12, article id 2857Article in journal (Refereed) Published
Abstract [en]

A family of non-ionic deep eutectic liquids has been developed based upon mixtures of solid N-alkyl derivatives of urea and acetamide that in some cases have melting points below room temperature. The eutectic behaviour and physical characteristics of a series of eleven eutectic mixtures are presented, along with a molecular dynamics study-supported hypothesis for the origin of the non-ideal mixing of these substances. Their use as solvents in applications ranging from natural product extraction to organic and polymer synthesis are demonstrated.

Place, publisher, year, edition, pages
MDPI, 2019. Vol. 20, no 12, article id 2857
Keywords [en]
deep-eutectic solvent, flickering cluster, acetamide-urea
National Category
Organic Chemistry
Research subject
Chemistry, Organic Chemistry
Identifiers
URN: urn:nbn:se:lnu:diva-86961DOI: 10.3390/ijms20122857ISI: 000473756000007PubMedID: 31212745Scopus ID: 2-s2.0-85068473566OAI: oai:DiVA.org:lnu-86961DiVA, id: diva2:1338621
Available from: 2019-07-23 Created: 2019-07-23 Last updated: 2019-08-29Bibliographically approved

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Suriyanarayanan, SubramanianOlsson, Gustaf D.Kathiravan, SuppanNdizeye, NatachaNicholls, Ian A.

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Suriyanarayanan, SubramanianOlsson, Gustaf D.Kathiravan, SuppanNdizeye, NatachaNicholls, Ian A.
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Department of Chemistry and Biomedical Sciences
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International Journal of Molecular Sciences
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