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Extensive accumulation of rare earth elements in estuarine sediments affected by leaching of acid sulfate soils
Linnaeus University, Faculty of Health and Life Sciences, Department of Biology and Environmental Science. Linnaeus University, Linnaeus Knowledge Environments, Water.ORCID iD: 0000-0002-3585-2209
Linnaeus University, Faculty of Health and Life Sciences, Department of Biology and Environmental Science.ORCID iD: 0000-0002-0635-3718
Geol Survey Finland GTK, Finland.
Åbo Akad Univ, Finland.
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2020 (English)In: Boreal environment research, ISSN 1239-6095, E-ISSN 1797-2469, Vol. 25, p. 105-120Article in journal (Refereed) Published
Abstract [en]

The concentrations, loads and speciation of rare earth elements (REEs) were studied in a 3.5 m thick mud depositional succession from an estuary in the Gulf of Bothnia. The uppermost 182.5 cm of the mud, estimated to have deposited from the early 1970s to 2011 (sampling year), had very high REE concentrations (596-1456 ppm) and accumulation rates (5.2-28 g m(-2) year(-1)). This was explained by large REE export from acid sulfate soils after they became efficiently drained with modern drainage techniques. Geochemical and synchrotron-based spectroscopic (XANES) analyses showed that the REEs in the mud are relatively firmly bound in non-clastic phases, likely adsorbed by clay minerals and also to some extent by iron oxyhydroxides. Below 182.5 cm, the REE concentrations successively decreased down to background values at the base at 3.5 m, reflecting less efficient drainage and leaching of the acid sulfate soils in previous decades and centuries.

Place, publisher, year, edition, pages
Finnish Environmental Inst , 2020. Vol. 25, p. 105-120
National Category
Environmental Sciences
Research subject
Natural Science, Environmental Science
Identifiers
URN: urn:nbn:se:lnu:diva-100056ISI: 000598188300001Scopus ID: 2-s2.0-85118393820OAI: oai:DiVA.org:lnu-100056DiVA, id: diva2:1518444
Available from: 2021-01-15 Created: 2021-01-15 Last updated: 2023-09-22Bibliographically approved

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Åström, Mats E.Yu, ChangxunPeltola, Pasi

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