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Resistance to a tyrosine kinase inhibitor mediated by changes to the conformation space of the kinase
Univ Fed Sao Carlos, Brazil.ORCID iD: 0000-0001-6086-3818
Univ Fed Sao Carlos, Brazil.
Univ Fed Sao Carlos, Brazil.
Linnaeus University, Faculty of Health and Life Sciences, Department of Chemistry and Biomedical Sciences. (Linnaeus Ctr Biomat Chem, BMC;CCBG)ORCID iD: 0000-0001-8696-3104
2023 (English)In: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 25, no 8, p. 6175-6183Article in journal (Refereed) Published
Abstract [en]

Gilteritinib is a highly selective and effective inhibitor of the FLT3/ITD mutated protein, and is used successfully in treating acute myeloid leukaemia (AML). Unfortunately, tumour cells gradually develop resistance to gilteritinib due to mutations in the molecular drug target. The atomistic details behind this observed resistance are not clear, since the protein structure of the complex is only available in the inactive state, while the drug binds better to the active state. To overcome this limitation, we used a computer-aided approach where we docked gilteritinib to the active site of FLT3/ITD and calculated the Gibbs free energy difference between the binding energies of the parental and mutant enzymes. These calculations agreed with experimental estimations for one mutation (F691L) but not the other (D698N). To further understand how these mutations operate, we used metadynamics simulations to study the conformational landscape of the activation process. Both mutants show a lower activation energy barrier which suggests that they are more likely to adopt an active state until inhibited, making the mutant enzymes more active. This suggests that a higher efficiency of tyrosine kinases contributes to resistance not only against type 2 but also against type 1 kinase inhibitors.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2023. Vol. 25, no 8, p. 6175-6183
National Category
Biochemistry and Molecular Biology
Research subject
Chemistry, Biochemistry
Identifiers
URN: urn:nbn:se:lnu:diva-119798DOI: 10.1039/d2cp05549jISI: 000929143700001PubMedID: 36752538Scopus ID: 2-s2.0-85148443652OAI: oai:DiVA.org:lnu-119798DiVA, id: diva2:1744024
Available from: 2023-03-16 Created: 2023-03-16 Last updated: 2023-08-31Bibliographically approved

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Friedman, Ran

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