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Determination of the Equilibrium Constants and UV-Absorption Spectra for Cu2+- Cl- Complexes in 1M HClO4
Department of Physical Chemistry, The Royal Institute of Technology, S-100 44, Stockholm 70, Sweden.
1976 (English)In: Journal of inorganic and nuclear chemistry, Vol. 38, no 8, p. 1525-1527Article in journal (Refereed) Published
Abstract [en]

The complex constants for the Cu(II)-chloride complexes CuCl+ and CuCl2 have been determined spectrophotometrically at 25°C and in 1 M HClO4. The evaluation procedure employed was a regression analysis for the simultaneous determination of complex constants and absorption spectra and yielded K1 = 2.3 ± 0.4 and K2 = 0.72 ± 0.09. There is a strong overlap between the 2 absorption spectra (λmax = 250 nm in both cases, ε1=530, , ε2 = 1620) which made it particularly necessary to arrange the numerical analysis in such a way that the spectral differences were fully exploited.

Place, publisher, year, edition, pages
1976. Vol. 38, no 8, p. 1525-1527
National Category
Other Environmental Engineering
Research subject
Environmental Science, Environmental technology
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URN: urn:nbn:se:lnu:diva-1452DOI: 10.1016/0022-1902(76)90021-XOAI: oai:DiVA.org:lnu-1452DiVA, id: diva2:308324
Available from: 2010-04-06 Created: 2010-04-06 Last updated: 2011-06-10Bibliographically approved

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Carlsson, Bo

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