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High resolution angle-resolved photoelectron spectrum of CO2, excited with polarized resonance radiation
Department of Physics, University of Uppsala.
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1986 (English)In: Journal of Electron Spectroscopy and Related Phenomena, ISSN 0368-2048, E-ISSN 1873-2526, Vol. 41, no 2, p. 205-223Article in journal (Refereed) Published
Abstract [en]

The He(I) excited and angle-resolved photoelectron spectrum of CO2 is investigated using a focussing VUV-polarizer. High resolution combined with the additional information given by comparing spectra taken at different angles permits detailed analysis of the vibrational structure. β-values are given for all vibrational components hitherto observed in the photoelectron spectrum of the ≈X, ≈A,≈B and ≈C electronic bands. Single excitations of the v3 mode with vibrational energies 181 meV in the estate and 279 meV in the ≈B-state are reported. The peak at 360 meV vibrational energy in the (≈C-state is reinterpreted as a single v3 excitation. The β-values of the most intense peaks are also measured using Ne(I) (16.67 and 16.85 eV), Ne(II) (26.86 and 26.95 eV) and He(II) (40.81) resonance radiations. 

Place, publisher, year, edition, pages
1986. Vol. 41, no 2, p. 205-223
National Category
Physical Sciences
Research subject
Natural Science, Physics
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URN: urn:nbn:se:lnu:diva-1498DOI: 10.1016/0368-2048(86)85004-6OAI: oai:DiVA.org:lnu-1498DiVA, id: diva2:308544
Available from: 2010-04-06 Created: 2010-04-06 Last updated: 2017-12-12Bibliographically approved

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Veenhuizen, Hans

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