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Kinetic resolution of chiral auxiliaries with C-2-symmetry by lipase-catalyzed alcoholysis and aminolysis
KTH, Sweden.
KTH, Sweden.
KTH, Sweden.
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1996 (English)In: Acta Chemica Scandinavica, ISSN 0904-213X, Vol. 50, no 10, 918-921 p.Article in journal (Refereed) Published
Abstract [en]

Three cyclic diols, 1,2-cyclohexanediol (1), 1,3-cyclohexanediol (2), and 1,3-cyclopentanediol (3), two acyclic unsaturated diols, 1,5-hexadiene-3,4-diol (4) and 1,7-octadiyne-3,6-diol (5), and a cyclic diamine, 1,2-cyclohexanediamine (6), have been kinetically resolved in alcoholysis and aminolysis reactions, catalyzed by Candida antarctica component B lipase, using S-ethyl thiooctanoate or ethyl octanoate as acyl donors. Acceptable stereoselectivity was achieved in most cases.

Place, publisher, year, edition, pages
1996. Vol. 50, no 10, 918-921 p.
Keyword [en]
ethyl-octanoate, transesterification, acid
National Category
Natural Sciences
Identifiers
URN: urn:nbn:se:lnu:diva-14105ISI: A1996VN35400009OAI: oai:DiVA.org:lnu-14105DiVA: diva2:440796
Note
Vn354 Times Cited:15 Cited References Count:14Available from: 2011-09-13 Created: 2011-09-13 Last updated: 2017-01-11Bibliographically approved

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Unelius, C. R.
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