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Rhodium-Catalyzed Oxidative Perfluoroalkenylation by Carbonyl Group Directed C-H Bond Activation
Linnaeus University, Faculty of Health and Life Sciences, Department of Chemistry and Biomedical Sciences. (BMC)ORCID iD: 0000-0003-0774-2528
Linnaeus University, Faculty of Health and Life Sciences, Department of Chemistry and Biomedical Sciences. Uppsala University. (BMC ; BBCL)ORCID iD: 0000-0002-0407-6542
2014 (English)In: European Journal of Organic Chemistry, ISSN 1434-193X, E-ISSN 1099-0690, no 32, 7211-7219 p.Article in journal (Refereed) Published
Abstract [en]

The selective activation of C-H bonds under mild Rh-III catalytic conditions has been developed for the perfluoroalkenylation of various cyclic and acyclic aromatic ketones. This protocol uses versatile reagents and mild conditions. It requires a very low catalyst loading and has exceptional functional group tolerance as well as provides products in good to excellent yields. An application of this approach was described for the preparation of perfluoroethyl acrylate derivatives of biologically active substances.

Place, publisher, year, edition, pages
2014. no 32, 7211-7219 p.
Keyword [en]
Homogeneous catalysis, C-H activation, Olefination, Rhodium, Regioselectivity, Fluorine
National Category
Organic Chemistry
Research subject
Chemistry, Organic Chemistry
Identifiers
URN: urn:nbn:se:lnu:diva-38550DOI: 10.1002/ejoc.201402904ISI: 000344624000018OAI: oai:DiVA.org:lnu-38550DiVA: diva2:769906
Available from: 2014-12-09 Created: 2014-12-09 Last updated: 2017-02-21Bibliographically approved

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Kathiravan, SubbanNicholls, Ian A.
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