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Rhodium(III)-catalysed aerobic synthesis of highly functionalized indoles from N-arylurea under mild conditions through C-H activation
Linnaeus University, Faculty of Health and Life Sciences, Department of Chemistry and Biomedical Sciences. (BMC)ORCID iD: 0000-0003-0774-2528
Linnaeus University, Faculty of Health and Life Sciences, Department of Chemistry and Biomedical Sciences. Uppsala University. (BMC ; BBCL)ORCID iD: 0000-0002-0407-6542
2014 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 50, no 95, 14964-14967 p.Article in journal (Refereed) Published
Abstract [en]

A Rh(III) catalysed amino arylation of alkynes using copper as the terminal oxidant for regeneration of the catalytically active species under aerobic conditions is described. This novel C-H activation reaction was applied to the synthesis of a wide range of substituted indoles from N-arylureas.

Place, publisher, year, edition, pages
2014. Vol. 50, no 95, 14964-14967 p.
National Category
Organic Chemistry
Research subject
Chemistry, Organic Chemistry
Identifiers
URN: urn:nbn:se:lnu:diva-39265DOI: 10.1039/c4cc06020bISI: 000344596700010OAI: oai:DiVA.org:lnu-39265DiVA: diva2:782287
Available from: 2015-01-20 Created: 2015-01-20 Last updated: 2017-02-21Bibliographically approved

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Kathiravan, SubbanNicholls, Ian A.
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