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Palladium Catalyzed Vinyltrifluoromethylation of Aryl Halides through Decarboxylative Cross-Coupling with 2-(Trifluoromethyl)acrylic Acid
Linnaeus University, Faculty of Health and Life Sciences, Department of Chemistry and Biomedical Sciences. (BBCL)ORCID iD: 0000-0003-0774-2528
Linnaeus University, Faculty of Health and Life Sciences, Department of Chemistry and Biomedical Sciences. Uppsala university. (BBCL;Linnaeus Ctr Biomat Chem, BMC)ORCID iD: 0000-0002-0407-6542
2015 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 17, p. 1874-1877Article in journal (Refereed) Published
Abstract [en]

An efficient Pd-catalyzed stereoselective vinyltrifluoromethylation of aryl halides, through decarboxylative cross-coupling with 2-(trifluoromethyl)acrylic acid is described. The ready availability of the starting materials, the high level of functional group tolerance, and excellentE/Z selectivity make this protocol a safe and operationally convenient strategy for efficient synthesis of vinyltrifluoromethyl derivatives.

Place, publisher, year, edition, pages
2015. Vol. 17, p. 1874-1877
National Category
Organic Chemistry
Research subject
Chemistry, Organic Chemistry
Identifiers
URN: urn:nbn:se:lnu:diva-42599DOI: 10.1021/acs.orglett.5b00551ISI: 000353314800015PubMedID: 25826014Scopus ID: 2-s2.0-84928014294OAI: oai:DiVA.org:lnu-42599DiVA, id: diva2:805614
Available from: 2015-04-15 Created: 2015-04-15 Last updated: 2018-11-02Bibliographically approved

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Kathiravan, SuppanNicholls, Ian A.

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