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Controlled switching of single-molecule junctions by mechanical motion of a phenyl ring
Kyoto University, Japan.
Kyoto University, Japan.
Kyoto University, Japan.
Kyoto University, Japan.
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2015 (English)In: Beilstein Journal of Nanotechnology, ISSN 2190-4286, Vol. 6, p. 2088-2095Article in journal (Refereed) Published
Abstract [en]

Mechanical methods for single-molecule control have potential for wide application in nanodevices and machines. Here we demonstrate the operation of a single-molecule switch made functional by the motion of a phenyl ring, analogous to the lever in a conventional toggle switch. The switch can be actuated by dual triggers, either by a voltage pulse or by displacement of the electrode, and electronic manipulation of the ring by chemical substitution enables rational control of the on-state conductance. Owing to its simple mechanics, structural robustness, and chemical accessibility, we propose that phenyl rings are promising components in mechanical molecular devices.

Place, publisher, year, edition, pages
2015. Vol. 6, p. 2088-2095
Keywords [en]
density functional theory, phenyl rings, quantum transport simulations, scanning tunneling microscopy, single-molecule switches
National Category
Materials Chemistry Condensed Matter Physics
Research subject
Physics, Condensed Matter Physics
Identifiers
URN: urn:nbn:se:lnu:diva-47379DOI: 10.3762/bjnano.6.213ISI: 000363840300001Scopus ID: 2-s2.0-84947910268OAI: oai:DiVA.org:lnu-47379DiVA, id: diva2:873555
Available from: 2015-11-24 Created: 2015-11-24 Last updated: 2017-12-01Bibliographically approved

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Paulsson, Magnus

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